Issue 98, 2014

Oscillatory carbonylation using alkyne-functionalised poly(ethylene glycol)

Abstract

In this study palladium-catalysed oscillatory carbonylation has been achieved using mono alkyne-terminated poly(ethylene glycol) methyl ether substrates. Reproducible, synchronised oscillations in pH and solution turbidity have been recorded over several days. A reaction network accounting for the observed phenomena has been proposed.

Graphical abstract: Oscillatory carbonylation using alkyne-functionalised poly(ethylene glycol)

Supplementary files

Article information

Article type
Communication
Submitted
28 Feb 2014
Accepted
16 Jun 2014
First published
17 Jun 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 15506-15508

Author version available

Oscillatory carbonylation using alkyne-functionalised poly(ethylene glycol)

L. Donlon and K. Novakovic, Chem. Commun., 2014, 50, 15506 DOI: 10.1039/C4CC01548G

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