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Issue 47, 2014
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Binary role of an ylide in formation of a terminal methylidene complex of niobium

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Abstract

The first structurally characterized niobium(V) complex possessing a terminal methylidene ligand is reported in high yield from the reaction of [(Ar′O)2Nb(CH3)2Cl] (Ar′ = (2,6-CHPh2)2-4-tBu-C6H2) and two equivalents of H2CPPh3.

Graphical abstract: Binary role of an ylide in formation of a terminal methylidene complex of niobium

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The article was received on 23 Feb 2014, accepted on 24 Apr 2014 and first published on 24 Apr 2014


Article type: Communication
DOI: 10.1039/C4CC01404A
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Chem. Commun., 2014,50, 6267-6269

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    Binary role of an ylide in formation of a terminal methylidene complex of niobium

    K. Searles, K. Keijzer, C. Chen, M. Baik and D. J. Mindiola, Chem. Commun., 2014, 50, 6267
    DOI: 10.1039/C4CC01404A

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