Issue 47, 2014
From the journal:

Chemical Communications

Binary role of an ylide in formation of a terminal methylidene complex of niobium†

Keith Searles,a   Karlijn Keijzer,b   Chun-Hsing Chen,b   Mu-Hyun Baikb  and  Daniel J. Mindiola*a  

* Corresponding authors

a Department of Chemistry, University of Pennsylvania, Philadelphia, PA, USA
E-mail: mindiola@sas.upenn.edu
Fax: +1-215-573-9711

b Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, IN, USA

Abstract

The first structurally characterized niobium(V) complex possessing a terminal methylidene ligand is reported in high yield from the reaction of [(Ar′O)2Nb(CH3)2Cl] (Ar′ = (2,6-CHPh2)2-4-tBu-C6H2) and two equivalents of H2CPPh3.

Graphical abstract: Binary role of an ylide in formation of a terminal methylidene complex of niobium

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Article information

DOI
https://doi.org/10.1039/C4CC01404A
Article type
Communication
Submitted
23 Feb 2014
Accepted
24 Apr 2014
First published
24 Apr 2014

Chem. Commun., 2014,50, 6267-6269

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Binary role of an ylide in formation of a terminal methylidene complex of niobium

K. Searles, K. Keijzer, C. Chen, M. Baik and D. J. Mindiola, Chem. Commun., 2014, 50, 6267 DOI: 10.1039/C4CC01404A

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