Issue 28, 2014
From the journal:

Chemical Communications

Slow relaxation in the first penta-aza Dy(iii) macrocyclic complex†

Emma L. Gavey,a   Yassine Beldjoudi,b   Jeremy M. Rawson,b   Theocharis C. Stamatatosa  and  Melanie Pilkington*a  

* Corresponding authors

a Department of Chemistry, Brock University, 500 Glenridge Avenue, Ontario, Canada
E-mail: mpilkington@brocku.ca

b Department of Chemistry and Biochemistry, University of Windsor, 401 Sunset Ave., Windsor, Ontario, Canada N9B 3P4

Abstract

A new macrocyclic complex DyCl3(LN5)·4H2O (1) has been prepared in which the Dy(III) ion is equatorially bound by an N5-donor macrocycle (LN5). Ac susceptibility data reveal slow relaxation of the magnetisation in zero field below 15 K with a distribution of relaxation rates.

Graphical abstract: Slow relaxation in the first penta-aza Dy(iii) macrocyclic complex

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Article information

DOI
https://doi.org/10.1039/C4CC00930D
Article type
Communication
Submitted
04 Feb 2014
Accepted
20 Feb 2014
First published
20 Feb 2014

Chem. Commun., 2014,50, 3741-3743

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Slow relaxation in the first penta-aza Dy(III) macrocyclic complex

E. L. Gavey, Y. Beldjoudi, J. M. Rawson, T. C. Stamatatos and M. Pilkington, Chem. Commun., 2014, 50, 3741 DOI: 10.1039/C4CC00930D

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