Issue 29, 2014
From the journal:

Chemical Communications

Synthesis of polycyclic substituted vinylarenes via a one-pot intramolecular aryl alkylation–N-tosylhydrazone insertion reaction†

Xin-Xing Wu,a   Ping-Xin Zhou,a   Li-Jing Wang,a   Peng-Fei Xu*a  and  Yong-Min Liang*a  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China
E-mail: liangym@lzu.edu.cn, xupf@lzu.edu.cn
Fax: +86-931-8912582
Tel: +86-931-8912582

Abstract

A novel method of a palladium-catalyzed/norbornene-mediated intramolecular C–H activation/N-tosylhydrazones insertion reaction is developed. In this process, various bicyclic or tricyclic substituted vinylarenes are obtained with high efficiency under mild conditions.

Graphical abstract: Synthesis of polycyclic substituted vinylarenes via a one-pot intramolecular aryl alkylation–N-tosylhydrazone insertion reaction

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Article information

DOI
https://doi.org/10.1039/C4CC00809J
Article type
Communication
Submitted
30 Jan 2014
Accepted
14 Feb 2014
First published
14 Feb 2014

Chem. Commun., 2014,50, 3882-3884

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Synthesis of polycyclic substituted vinylarenes via a one-pot intramolecular aryl alkylation–N-tosylhydrazone insertion reaction

X. Wu, P. Zhou, L. Wang, P. Xu and Y. Liang, Chem. Commun., 2014, 50, 3882 DOI: 10.1039/C4CC00809J

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