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Issue 29, 2014
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Palladium-catalyzed aerobic oxidative coupling of enantioenriched primary allylic amines with sulfonyl hydrazides leading to optically active allylic sulfones

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Abstract

A range of highly enantioenriched primary allylic amines underwent palladium-catalyzed oxidative coupling with sulfonyl hydrazides open to air at room temperature to give structurally diverse allylic sulfones in moderate to excellent yields with excellent retention of ee.

Graphical abstract: Palladium-catalyzed aerobic oxidative coupling of enantioenriched primary allylic amines with sulfonyl hydrazides leading to optically active allylic sulfones

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Publication details

The article was received on 13 Jan 2014, accepted on 13 Feb 2014 and first published on 17 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC00275J
Citation: Chem. Commun., 2014,50, 3802-3805

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    Palladium-catalyzed aerobic oxidative coupling of enantioenriched primary allylic amines with sulfonyl hydrazides leading to optically active allylic sulfones

    T. Wang, F. Wang, F. Yang and S. Tian, Chem. Commun., 2014, 50, 3802
    DOI: 10.1039/C4CC00275J

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