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Issue 29, 2014
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Palladium-catalyzed aerobic oxidative coupling of enantioenriched primary allylic amines with sulfonyl hydrazides leading to optically active allylic sulfones

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Abstract

A range of highly enantioenriched primary allylic amines underwent palladium-catalyzed oxidative coupling with sulfonyl hydrazides open to air at room temperature to give structurally diverse allylic sulfones in moderate to excellent yields with excellent retention of ee.

Graphical abstract: Palladium-catalyzed aerobic oxidative coupling of enantioenriched primary allylic amines with sulfonyl hydrazides leading to optically active allylic sulfones

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Article information


Submitted
13 Jan 2014
Accepted
13 Feb 2014
First published
17 Feb 2014

Chem. Commun., 2014,50, 3802-3805
Article type
Communication

Palladium-catalyzed aerobic oxidative coupling of enantioenriched primary allylic amines with sulfonyl hydrazides leading to optically active allylic sulfones

T. Wang, F. Wang, F. Yang and S. Tian, Chem. Commun., 2014, 50, 3802
DOI: 10.1039/C4CC00275J

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