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Issue 22, 2014
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Synthesis, structure and reactivity of group 4 corrole complexes

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Abstract

A series of early transition metal corrole complexes has been prepared via salt metathesis with the corresponding lithium corrole. Their characterization by single crystal X-ray diffraction, NMR, and absorption spectroscopy is described. Organometallic derivatives of the titanium complex were obtained via treatment of 2 with NaCp* or ClMgCH2SiMe3.

Graphical abstract: Synthesis, structure and reactivity of group 4 corrole complexes

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Article information


Submitted
02 Jan 2014
Accepted
30 Jan 2014
First published
30 Jan 2014

Chem. Commun., 2014,50, 2922-2924
Article type
Communication

Synthesis, structure and reactivity of group 4 corrole complexes

R. Padilla, H. L. Buckley, A. L. Ward and J. Arnold, Chem. Commun., 2014, 50, 2922
DOI: 10.1039/C4CC00037D

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