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Issue 18, 2014
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A singly bonded amido-distannyne: H2 activation and isocyanide coordination

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Abstract

The first amido-distannyne, LSnSnL (L = –N(Ar)(SiPri3), Ar = C6H2{C(H)Ph2}2Pri-2,6,4), has been prepared and shown to possess a very long Sn–Sn single bond; the compound activates dihydrogen under ambient conditions to give LSn(μ-H)2SnL, and reacts with ButNC to give a stable adduct complex, L(ButNC)SnSn(CNBut)L.

Graphical abstract: A singly bonded amido-distannyne: H2 activation and isocyanide coordination

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Publication details

The article was received on 20 Dec 2013, accepted on 14 Jan 2014 and first published on 15 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC49651A
Citation: Chem. Commun., 2014,50, 2321-2323

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    A singly bonded amido-distannyne: H2 activation and isocyanide coordination

    T. J. Hadlington and C. Jones, Chem. Commun., 2014, 50, 2321
    DOI: 10.1039/C3CC49651A

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