Issue 32, 2014
From the journal:

Chemical Communications

Thiadiazole dioxide-fused picene: acceptor ability, anion radical formation, and n-type charge transport characteristics†

Yongfa Xie,a   Yoshiaki Shuku,a   Michio M. Matsushita*a  and  Kunio Awaga*ab  

* Corresponding authors

a Department of Chemistry & Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan
E-mail: mmmatsushita@nagoya-u.jp, Awaga@mbox.chem.nagoya-u.ac.jp

b CREST, JST, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan

Abstract

Picene, which is an organic p-channel semiconductor and a component of superconductors, was derivatized with a thiadiazole-dioxide moiety to afford a novel acceptor molecule (PTDAO2). PTDAO2 can form stable anion radical species in solution and as a crystal, and its neutral crystalline thin film exhibits n-type transistor characteristics.

Graphical abstract: Thiadiazole dioxide-fused picene: acceptor ability, anion radical formation, and n-type charge transport characteristics

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC49500K
Article type
Communication
Submitted
15 Dec 2013
Accepted
23 Jan 2014
First published
27 Jan 2014

Chem. Commun., 2014,50, 4178-4180

Permissions

Request permissions

Thiadiazole dioxide-fused picene: acceptor ability, anion radical formation, and n-type charge transport characteristics

Y. Xie, Y. Shuku, M. M. Matsushita and K. Awaga, Chem. Commun., 2014, 50, 4178 DOI: 10.1039/C3CC49500K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements