Issue 15, 2014
From the journal:

Chemical Communications

Highly diastereoselective cyclopropanation of α-methylstyrene catalysed by a C2-symmetrical chiral iron porphyrin complex†

Daniela Intrieri,a   Stéphane Le Gac,b   Alessandro Caselli,a   Eric Rose,c   Bernard Boitrel*b  and  Emma Gallo*a  

* Corresponding authors

a Dipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, 20133 Milano, Italy
E-mail: emma.gallo@unimi.it
Fax: +39-02-50314405
Tel: +39-02-50314374

b Institut des Sciences Chimiques de Rennes, UMR CNRS 6226, Université de Rennes 1, 263 avenue du Général Leclerc, CS 74205, 35042 Rennes Cedex, France
E-mail: bernard.boitrel@univ-rennes1.fr
Fax: +33 2 2323 5637
Tel: +33 2 2323 5856

c Université P. et M. Curie, UPMC Paris 06, IPCM, UMR CNRS 7201, Bâtiment F, 4 Place Jussieu, 75252 Paris Cedex 05, France

Abstract

A new chiral iron porphyrin-based catalyst performed α-methylstyrene stereoselective cyclopropanation with excellent yields (up to 99%), enantio- and diastereoselectivities (eetrans up to 87%, trans/cis ratios up to 99 : 1) and outstanding TON and TOF values (up to 20 000 and 120 000 h−1 respectively).

Graphical abstract: Highly diastereoselective cyclopropanation of α-methylstyrene catalysed by a C2-symmetrical chiral iron porphyrin complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC48605B
Article type
Communication
Submitted
11 Nov 2013
Accepted
11 Dec 2013
First published
12 Dec 2013

Chem. Commun., 2014,50, 1811-1813

Author version available

Download author version (PDF)

Permissions

Request permissions

Highly diastereoselective cyclopropanation of α-methylstyrene catalysed by a C2-symmetrical chiral iron porphyrin complex

D. Intrieri, S. Le Gac, A. Caselli, E. Rose, B. Boitrel and E. Gallo, Chem. Commun., 2014, 50, 1811 DOI: 10.1039/C3CC48605B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements