Two- and one-step cooperative spin transitions in Hofmann-like clathrates with enhanced loading capacity†
Abstract
Structural, magnetic, calorimetric and Mössbauer studies of the cooperative spin crossover naphthalene and nitrobenzene clathrates of the novel FeII Hofmann-like porous metal–organic framework {Fe(bpb)[Pt(CN)4]}·2Guest are described (bpb = bis(4-pyridyl)butadiyne).