Over the past few decades, the semipinacol rearrangement has been widely applied in the field of organic synthesis. However, its catalytic asymmetric version has not caught much attention until the beginning of the 21st century. Significant breakthroughs have been made due to the efforts of organic chemists. These important progressions are summarized in this paper.
S. Wang, B. Li and Y. Tu, Chem. Commun., 2014, 50, 2393 DOI: 10.1039/C3CC48547A
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