Issue 7, 2014
From the journal:

Chemical Communications

A mild and catalyst-free conversion of solid phase benzylidenemalononitrile/benzylidenemalonate to N-benzylidene-amine and its application for fluorescence detection of primary alkyl amine vapor†

Liqi Shi,ab   Yanyan Fu,a   Chao He,a   Defeng Zhu,a   Yixun Gao,ab   Yuerong Wang,ab   Qingguo He,*a   Huimin Caoa  and  Jiangong Cheng*a  

* Corresponding authors

a State Key Lab of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Changning Road 865, Shanghai 200050, China
E-mail: hqg@mail.sim.ac.cn, jgcheng@mail.sim.ac.cn

b Graduate School of the Chinese Academy of Sciences, Yuquan Road 19, Beijing 100039, China

Abstract

A new rapid and catalyst-free solid/vapor reaction between benzylidenemalonate/benzylidenemalononitrile and primary alkyl amines was found. With these as sensory units of fluorescent polymers, probes for primary amine vapor with high sensitivity and selectivity were developed.

Graphical abstract: A mild and catalyst-free conversion of solid phase benzylidenemalononitrile/benzylidenemalonate to N-benzylidene-amine and its application for fluorescence detection of primary alkyl amine vapor

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Article information

DOI
https://doi.org/10.1039/C3CC48299E
Article type
Communication
Submitted
30 Oct 2013
Accepted
12 Nov 2013
First published
13 Nov 2013

Chem. Commun., 2014,50, 872-874

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A mild and catalyst-free conversion of solid phase benzylidenemalononitrile/benzylidenemalonate to N-benzylidene-amine and its application for fluorescence detection of primary alkyl amine vapor

L. Shi, Y. Fu, C. He, D. Zhu, Y. Gao, Y. Wang, Q. He, H. Cao and J. Cheng, Chem. Commun., 2014, 50, 872 DOI: 10.1039/C3CC48299E

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