Issue 7, 2014
From the journal:

Chemical Communications

Thermally/hydrolytically stable covalent organic frameworks from a rigid macrocyclic host†

Jing-Ru Song,a   Junliang Sun,*b   Junmin Liu,*c   Zhi-Tang Huanga  and  Qi-Yu Zheng*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China
E-mail: zhengqy@iccas.ac.cn
Fax: +86 10 6255 4449
Tel: +86 010 6265 2811

b Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
E-mail: junliang.sun@pku.edu.cn

c Klghei of Environment and Energy Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: liujunm@mail.sysu.edu.cn

Abstract

Two new 2D COFs were synthesized from triformylcyclotrianisylene, which show not only thermal stability but also hydrolytic stability. CTV-COF-1 with smaller pore size stored a high hydrogen level of 1.3 wt% at low pressure, while CTV-COF-2 with larger pore size showed superior carbon dioxide uptake, up to 250 cm3 g−1 at 298 K and 50 bar.

Graphical abstract: Thermally/hydrolytically stable covalent organic frameworks from a rigid macrocyclic host

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Article information

DOI
https://doi.org/10.1039/C3CC47652A
Article type
Communication
Submitted
05 Oct 2013
Accepted
24 Oct 2013
First published
24 Oct 2013

Chem. Commun., 2014,50, 788-791

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Thermally/hydrolytically stable covalent organic frameworks from a rigid macrocyclic host

J. Song, J. Sun, J. Liu, Z. Huang and Q. Zheng, Chem. Commun., 2014, 50, 788 DOI: 10.1039/C3CC47652A

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