Issue 52, 2014
From the journal:

Chemical Communications

Charge instability of symmetry broken dipolar states in quadrupolar and octupolar triphenylamine derivatives†

Shanmugam Easwaramoorthi,*ab   Pichandi Thamaraiselvi,a   Kumaraguru Duraimurugan,c   Arockiam Jesin Beneto,c   Ayyanar Siva*c  and  Balachandran Unni Naira  

* Corresponding authors

a Chemical Laboratory, CSIR-Central Leather Research Institute, Adyar, Chennai, India
E-mail: moorthi@clri.res.in
Fax: +91-44-24411630

b CSIR-Network of Institutes for Solar Energy (NISE), India

c Department of Inorganic Chemistry, Madurai Kamaraj University, Madurai, India
E-mail: drasiva@gmail.com

Abstract

The quadrupolar and octupolar cyano triphenylamines shows symmetry broken dipolar charge transfer state, however, its stability can be controlled by the rotation of N–C bond of amino and phenylene moiety.

Graphical abstract: Charge instability of symmetry broken dipolar states in quadrupolar and octupolar triphenylamine derivatives

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Article information

DOI
https://doi.org/10.1039/C3CC47514J
Article type
Communication
Submitted
01 Oct 2013
Accepted
06 Apr 2014
First published
07 Apr 2014

Chem. Commun., 2014,50, 6902-6905

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Charge instability of symmetry broken dipolar states in quadrupolar and octupolar triphenylamine derivatives

S. Easwaramoorthi, P. Thamaraiselvi, K. Duraimurugan, A. J. Beneto, A. Siva and B. U. Nair, Chem. Commun., 2014, 50, 6902 DOI: 10.1039/C3CC47514J

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