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Issue 20, 2014
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Unusual activation of H2 by reduced cobalt complexes supported by a PNP pincer ligand

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Abstract

The reactivity of cobalt complexes supported by a PNP pincer ligand towards H2 varies depending on whether the N-donor atom is protonated; the synthesis of [(HPNP)CoCl(H)2] (2), [(PNP)CoH]2 (4), and the trihydride species [(HPNP)CoH3] (7) (HPNP = HN(CH2CH2PiPr2)2) are described.

Graphical abstract: Unusual activation of H2 by reduced cobalt complexes supported by a PNP pincer ligand

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Article information


Submitted
07 Aug 2013
Accepted
16 Jan 2014
First published
22 Jan 2014

Chem. Commun., 2014,50, 2612-2614
Article type
Communication

Unusual activation of H2 by reduced cobalt complexes supported by a PNP pincer ligand

S. S. Rozenel, R. Padilla, C. Camp and J. Arnold, Chem. Commun., 2014, 50, 2612
DOI: 10.1039/C3CC46018E

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