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Issue 46, 2013
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A novel neutral organic electron donor with record half-wave potential

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Abstract

Tricyclic donor 26 has been prepared and is the most reducing neutral ground-state organic molecule known, with an oxidation potential 260 mV more negative than the previous record. Cyclic voltammetry shows that a 2-electron reversible redox process occurs in DMF as solvent at −1.46 V vs. Ag/AgCl.

Graphical abstract: A novel neutral organic electron donor with record half-wave potential

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Article information


Submitted
20 Aug 2013
Accepted
10 Oct 2013
First published
11 Oct 2013

Org. Biomol. Chem., 2013,11, 8073-8081
Article type
Paper

A novel neutral organic electron donor with record half-wave potential

H. S. Farwaha, G. Bucher and J. A. Murphy, Org. Biomol. Chem., 2013, 11, 8073
DOI: 10.1039/C3OB41701H

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