Factors on the separation of photogenerated charges and the charge dynamics in oxide/ZnFe2O4 composites

Abstract

Four oxide/ZnFe₂O₄ composites (WO₃/ZnFe₂O₄, α-Bi₂O₃/ZnFe₂O₄, TiO₂/ZnFe₂O₄ and SnO₂/ZnFe₂O₄) were synthesized with 2 : 1, 4 : 1, 6 : 1 and 8 : 1 molar ratios of (W, Bi, Ti and Sn)/Zn. From the energy band structure, all composites can satisfy the energy level matching between their components (oxides and ZnFe₂O₄). For WO₃/ZnFe₂O₄ and α-Bi₂O₃/ZnFe₂O₄, almost all of the molar ratios have stronger photovoltaic responses than each component before compounding, but the other two composites present the opposite result. Due to the different charge dynamics, the photovoltaic characteristics of four composites with molar ratio 4 : 1 did not satisfy the “inverted region effect”. Time-resolved fluorescence spectroscopy provided direct evidence of energy transfer between components. Then we discussed the factors affecting the separation of photogenerated charges and the charge dynamics from surface area, band gap, conduction band edge, energy level matching and overlapping of wave functions. The research results also provide a way to select composite systems as photoanodes for dye-sensitized solar cells.