Issue 35, 2013
From the journal:

Journal of Materials Chemistry A

Trigonal prism or octahedron: the conformational change of a dendritic six-node ligand in MOFs†

Jiangtao Jia,a   Fuxing Sun,a   Heping Ma,a   Lei Wang,a   Kun Cai,a   Zheng Bian,*b   Lianxun Gaob  and  Guangshan Zhu*a  

* Corresponding authors

a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
E-mail: zhugs@jlu.edu.cn
Fax: +86-431-85168331
Tel: +86-431-85168887

b State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China
E-mail: bianzh@ciac.jl.cn
Fax: +86-431-85697831
Tel: +86-431- 85262291

Abstract

A new dendritic aromatic six-node ligand has been used to construct a MOF. It takes an octahedral and trigonal prismatic conformation in JUC-103 and JUC-104, respectively. JUC-103 exhibits high ethane uptake and has the separation ability for ethane to nitrogen. JUC-104 has an unusual (6,12)-connected CaSi2 topology.

Graphical abstract: Trigonal prism or octahedron: the conformational change of a dendritic six-node ligand in MOFs

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Article information

DOI
https://doi.org/10.1039/C3TA11840A
Article type
Communication
Submitted
10 May 2013
Accepted
05 Jul 2013
First published
08 Jul 2013

J. Mater. Chem. A, 2013,1, 10112-10115

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Trigonal prism or octahedron: the conformational change of a dendritic six-node ligand in MOFs

J. Jia, F. Sun, H. Ma, L. Wang, K. Cai, Z. Bian, L. Gao and G. Zhu, J. Mater. Chem. A, 2013, 1, 10112 DOI: 10.1039/C3TA11840A

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