Issue 16, 2013
From the journal:

Journal of Materials Chemistry A

A hybrid metal phosphate–phosphite material grafted with electron deficient organic components showing interesting fluorescent and photosensitive properties†

Jie Zhang,a   Zhenguo Yao,a   Shijun Liao,a   Jingcao Daib  and  Zhiyong Fu*a  

* Corresponding authors

a The Key Lab of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong, China
E-mail: zyfu@scut.edu.cn
Fax: +86 20 8711-2965

b Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, Fujian, China
E-mail: jcdai@hqu.edu.cn
Fax: +86 595 2269-0569

Abstract

A new hybrid organic zinc phosphate–phosphite with a tris (4-pyridyl) triazine molecule embedded in the cavity of an extra-large 24-ring channel has been synthesized and characterized. A strong luminescence emission is observed, which is due to the close packed array of organic ligands. The covalent coupling of fluorescent and photochromic components builds a novel phosphate-based photoactive dyad system.

Graphical abstract: A hybrid metal phosphate–phosphite material grafted with electron deficient organic components showing interesting fluorescent and photosensitive properties

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Article information

DOI
https://doi.org/10.1039/C3TA10478H
Article type
Communication
Submitted
31 Jan 2013
Accepted
06 Mar 2013
First published
06 Mar 2013

J. Mater. Chem. A, 2013,1, 4945-4948

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A hybrid metal phosphate–phosphite material grafted with electron deficient organic components showing interesting fluorescent and photosensitive properties

J. Zhang, Z. Yao, S. Liao, J. Dai and Z. Fu, J. Mater. Chem. A, 2013, 1, 4945 DOI: 10.1039/C3TA10478H

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