Issue 9, 2013

In situ high pressure NMR study of the direct synthesis of LiAlH4

Abstract

27Al and 7Li wide-line NMR spectroscopy incorporating a high pressure NMR apparatus has allowed the first in situ study of the solvent mediated, direct synthesis of an alanate, thus overcoming the dearth of analytical techniques available to study phenomena occurring in a pressurised slurry. In contrast to the decomposition reaction, the elucidated hydrogenation pathway does not proceed through the hexahydride intermediate.

Graphical abstract: In situ high pressure NMR study of the direct synthesis of LiAlH4

Supplementary files

Article information

Article type
Communication
Submitted
16 Jan 2013
Accepted
17 Jan 2013
First published
21 Jan 2013

J. Mater. Chem. A, 2013,1, 2974-2977

In situ high pressure NMR study of the direct synthesis of LiAlH4

T. D. Humphries, D. Birkmire, B. C. Hauback, G. S. McGrady and C. M. Jensen, J. Mater. Chem. A, 2013, 1, 2974 DOI: 10.1039/C3TA10239D

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