A supramoleculear self-assembled flexible open framework based on the coordination of honeycomb layers possessing octahedral and tetrahedral CoII geometries

Yang Zou; Yuanyuan Li; Chaoyong Yu; Fei Yin; Myoung Soo Lah

doi:10.1039/C3RA43290D

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A supramoleculear self-assembled flexible open framework based on the coordination of honeycomb layers possessing octahedral and tetrahedral Co^II geometries†

Yang Zou,*^a Yuanyuan Li,^a Chaoyong Yu,^a Fei Yin^a and Myoung Soo Lah*^b

Author affiliations

* Corresponding authors

^a Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou, China
E-mail: zouyang@zstu.edu.cn

^b Interdisciplinary School Green Energy, Ulsan National Institute Science & Technology, Ulsan 689798, South Korea
E-mail: mslah@unist.ac.kr

Abstract

A flexible open framework, {[Co₂(L)Cl(DMF)₂(H₂O)]·S_x}_n (H₃L = 4,4′,4′′-[1,3,5-benzenetriyltris(carbonylimino)]-trisbenzoic acid, DMF = dimethylformamide), was constructed based on a honeycomb coordination subunit with both octahedral and tetrahedral Co^II sites, showing moderate MeOH sorption and antiferromagnetic properties.

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Article information

DOI: https://doi.org/10.1039/C3RA43290D
Article type: Communication
Submitted: 28 Jun 2013
Accepted: 12 Aug 2013
First published: 13 Aug 2013

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RSC Adv., 2013,3, 19889-19893

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A supramoleculear self-assembled flexible open framework based on the coordination of honeycomb layers possessing octahedral and tetrahedral Co^II geometries

Y. Zou, Y. Li, C. Yu, F. Yin and M. S. Lah, RSC Adv., 2013, 3, 19889 DOI: 10.1039/C3RA43290D

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