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Issue 48, 2013
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Efficient ipso-nitration of arylboronic acids with iron nitrate as the nitro source

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Abstract

A novel, simple and efficient ipso-nitration of arylboronic acids with iron nitrate has been developed. The protocol uses readily available arylboronic acids as the starting materials, inexpensive iron nitrate (0.5 equiv.) as the nitro source without addition of an additive, and the corresponding nitroarenes were obtained in good to excellent yields.

Graphical abstract: Efficient ipso-nitration of arylboronic acids with iron nitrate as the nitro source

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Publication details

The article was received on 14 Sep 2013, accepted on 15 Oct 2013 and first published on 22 Oct 2013


Article type: Communication
DOI: 10.1039/C3RA45118F
RSC Adv., 2013,3, 25602-25604

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    Efficient ipso-nitration of arylboronic acids with iron nitrate as the nitro source

    M. Jiang, H. Yang, Y. Li, Z. Jia and H. Fu, RSC Adv., 2013, 3, 25602
    DOI: 10.1039/C3RA45118F

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