A novel efficient ligand-free CuI/TBAB catalytic system has been developed for Heck reaction in water without the protection of an inert atmosphere. Both aryl iodides and aryl bromides containing electron-deficient and electron-donating groups reacted smoothly and afforded the corresponding products in moderate to good yields.
Y. Wang, Q. Yang, L. Yang, J. Shi and M. Zhang, RSC Adv., 2013, 3, 21251 DOI: 10.1039/C3RA44819C
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