Catalytic pyrolysis of microalga Chlorella pyrenoidosa for production of ethylene, propylene and butene

Abstract

This paper investigated the process of catalytic pyrolysis of lipid-rich microalga Chlorella pyrenoidosa for the production of light olefins (ethylene, propylene and butene). A modified ZSM-5 zeolite catalyst was used in the reactions, and it had high selectivity for the light olefins production. The catalytic pyrolysis performances of microalga Chlorella pyrenoidosa in nitrogen and steam reaction atmospheres were investigated. The catalytic pyrolysis performances in one-step and two-step processes were investigated and compared. The effects of reaction temperatures and water flow rates on the catalytic pyrolysis performances were also explored. The results showed that higher yield of light olefins was obtained in the steam reaction atmosphere as compared with that in the nitrogen atmosphere. The carbon yield of light olefins obtained from two-step catalytic pyrolysis was nearly three times that from one-step catalytic pyrolysis. The two-step catalytic pyrolysis process also facilitated the production of aromatic hydrocarbons in the liquid products. The maximum carbon yield of light olefins could reach 31.9% in the two-step process under the reaction temperature of 923 K and water flow rate of 30 ml h⁻¹.