Issue 44, 2013
From the journal:

RSC Advances

Nickel catalyzed one pot synthesis of biaryls under air at room temperature†

Aparna P. I. Bhat,a   Fawad Inamb  and  Badekai Ramachandra Bhat*a  

* Corresponding authors

a Catalysis and Materials Laboratory, Department of Chemistry, National Institute of Technology Karnataka, Srinivasanagar, Surathkal, India
E-mail: chandpoorna@yahoo.com
Fax: +91 824-2474033
Tel: +91 824-2474000 ext. 3204

b Faculty of Engineering and Environment, Northumbria University, Newcastle upon Tyne, UK

Abstract

A practical, room temperature catalytic system has been developed for the synthesis of biaryls in one step from the homocoupling of in situ generated Grignard reagents using a nickel(II) complex. The use of atmospheric oxygen as the oxidant makes the system environmentally friendly. The reaction system is compatible with diverse functionality to afford biaryls in appreciable yields.

Graphical abstract: Nickel catalyzed one pot synthesis of biaryls under air at room temperature

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Article information

DOI
https://doi.org/10.1039/C3RA43363C
Article type
Paper
Submitted
02 Jul 2013
Accepted
06 Sep 2013
First published
06 Sep 2013

RSC Adv., 2013,3, 22191-22198

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Nickel catalyzed one pot synthesis of biaryls under air at room temperature

A. P. I. Bhat, F. Inam and B. R. Bhat, RSC Adv., 2013, 3, 22191 DOI: 10.1039/C3RA43363C

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