Issue 43, 2013
From the journal:

RSC Advances

Highly regioselective iridium-catalyzed and samarium-promoted coupling of allylic carbonates with ketones: a new approach towards homoallylic alcohols†

Wei Liu,a   Liang Zhang,a   Weikang Yanga  and  Xiaoming Zhao*a  

* Corresponding authors

a Department of Chemistry, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, 1239 Siping Road, Shanghai 200092, P. R. China
E-mail: xmzhao08@mail.tongji.edu.cn
Fax: +86-21-65981376

Abstract

A highly regioselective Ir-catalyzed and Sm-promoted coupling of allylic carbonates with ketones has been realized, which provides the homoallylic alcohols in up to 89% yields. This strategy gives a convenient method for the synthesis of liquid crystals with a mono-fluorinated quaternary carbon chain.

Graphical abstract: Highly regioselective iridium-catalyzed and samarium-promoted coupling of allylic carbonates with ketones: a new approach towards homoallylic alcohols

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Article information

DOI
https://doi.org/10.1039/C3RA43199A
Article type
Communication
Submitted
25 Jun 2013
Accepted
30 Aug 2013
First published
02 Sep 2013

RSC Adv., 2013,3, 19917-19919

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Highly regioselective iridium-catalyzed and samarium-promoted coupling of allylic carbonates with ketones: a new approach towards homoallylic alcohols

W. Liu, L. Zhang, W. Yang and X. Zhao, RSC Adv., 2013, 3, 19917 DOI: 10.1039/C3RA43199A

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