Issue 34, 2013
From the journal:

RSC Advances

A tetrameric hetero-octanuclear cyclic helicate formed from a bridging ligand with two inequivalent binding sites†

A. J. Metherella  and  M. D. Ward*a  

* Corresponding authors

a Department of Chemistry, University of Sheffield, Sheffield S3 7HF, UK
E-mail: m.d.ward@sheffield.ac.uk

Abstract

A bis-bidentate bridging ligand H2L with inequivalent hard and soft binding sites (catecholate and pyrazolyl-pyridine, respectively) reacts with a mixture of Ti(IV) and Zn(II) ions to afford an octanuclear heterometallic Ti4Zn4 cyclic helicate formed from four dinuclear {TiZn(μ-L)2} units connected in a ring via methoxide ions.

Graphical abstract: A tetrameric hetero-octanuclear cyclic helicate formed from a bridging ligand with two inequivalent binding sites

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Article information

DOI
https://doi.org/10.1039/C3RA42598C
Article type
Communication
Submitted
28 May 2013
Accepted
05 Jul 2013
First published
08 Jul 2013
This article is Open Access
Creative Commons BY license

RSC Adv., 2013,3, 14281-14285

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A tetrameric hetero-octanuclear cyclic helicate formed from a bridging ligand with two inequivalent binding sites

A. J. Metherell and M. D. Ward, RSC Adv., 2013, 3, 14281 DOI: 10.1039/C3RA42598C

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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