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Issue 8, 2013
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Luminescent properties of passivated europium(iii)-doped rare earth oxide sub-10 nm nanoparticles

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Abstract

Passivated nanoparticles of europium(III)-doped yttrium, lanthanum and gadolinium oxides were synthesized by a modified sol–gel method and their luminescent properties were studied. The passivation of the nanoparticles surface is confirmed by infrared spectroscopy. Gadolinium and yttrium oxides crystalize as cubic phases while the lanthanum oxide has hexagonal phase. The emission spectra of the samples show broad transitions attributed to europium(III) ions probably due to structure disorder caused by the size and also by the high surface/volume ratio of the nanoparticles. The Judd–Ofelt intensity parameters were obtained from the emission spectra. The passivation of the nanoparticles surface, with trioctylphosphine oxide, does not significantly alter the values of Ω2 and Ω4 parameters and slightly increases the emission quantum efficiency of the nanoparticles that possesses lower values of Ω2 parameter than bulk samples.

Graphical abstract: Luminescent properties of passivated europium(iii)-doped rare earth oxide sub-10 nm nanoparticles

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Article information


Submitted
16 Oct 2012
Accepted
12 Dec 2012
First published
13 Dec 2012

RSC Adv., 2013,3, 2794-2801
Article type
Paper

Luminescent properties of passivated europium(III)-doped rare earth oxide sub-10 nm nanoparticles

R. D. L. Gaspar, E. M. Rodrigues, I. O. Mazali and F. A. Sigoli, RSC Adv., 2013, 3, 2794
DOI: 10.1039/C2RA22532H

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