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Issue 19, 2013
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Supramolecular guests in solvent driven block copolymerassembly: from internally structured nanoparticles to micelles

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Abstract

Supramolecular interactions between different hydrogen-bonding guests and poly(2-vinylpyridine)-block-poly(styrene) can be exploited to prepare remarkably diverse self-assembled nanostructures in dispersion from a single block copolymer (BCP). The characteristics of the BCP can be efficiently controlled by tailoring the properties of a guest which preferentially binds to the P2VP block. For example, the incorporation of a hydrophobic guest creates a hydrophobic BCP complex that forms phase separated nanoparticles upon self-assembly. Conversely, the incorporation of a hydrophilic guest results in an amphiphilic BCP complex that forms spherical micelles in water. The ability to tune the self-assembly behavior and access dramatically different nanostructures from a single BCP substrate demonstrates the exceptional versatility of the self-assembly of BCPs driven by supramolecular interactions. This approach represents a new methodology that will enable the further design of complex, responsive self-assembled nanostructures.

Graphical abstract: Supramolecular guests in solvent driven block copolymer assembly: from internally structured nanoparticles to micelles

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Supplementary files

Article information


Submitted
08 Jun 2013
Accepted
01 Jul 2013
First published
05 Jul 2013

Polym. Chem., 2013,4, 5038-5042
Article type
Communication

Supramolecular guests in solvent driven block copolymer assembly: from internally structured nanoparticles to micelles

D. Klinger, M. J. Robb, J. M. Spruell, N. A. Lynd, C. J. Hawker and L. A. Connal, Polym. Chem., 2013, 4, 5038
DOI: 10.1039/C3PY00750B

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