Issue 8, 2013
From the journal:

Polymer Chemistry

SET-LRP of N-(2-hydroxypropyl)methacrylamide in H2O†

Nga Hang Nguyen,a   Cesar Rodriguez-Emmenegger,ab   Eduard Brynda,b   Zdenka Sedlakovab  and  Virgil Percec*a  

* Corresponding authors

a Roy & Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, USA
E-mail: percec@sas.upenn.edu

b Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, v.v.i., Prague 16206, Czech Republic

Abstract

Cu(0) wire-catalyzed SET-LRP of N-(2-hydroxypropyl)methacrylamide (HPMA) initiated with methyl 2-chloropropionate (MCP) in H2O at 50 °C exhibited linear kinetics up to 90% conversion using 0.5 equivalents of Me6-TREN with respect to initiator concentration.

Graphical abstract: SET-LRP of N-(2-hydroxypropyl)methacrylamide in H2O

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Article information

DOI
https://doi.org/10.1039/C3PY00220A
Article type
Communication
Submitted
12 Feb 2013
Accepted
20 Feb 2013
First published
21 Feb 2013

Polym. Chem., 2013,4, 2424-2427

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SET-LRP of N-(2-hydroxypropyl)methacrylamide in H2O

N. H. Nguyen, C. Rodriguez-Emmenegger, E. Brynda, Z. Sedlakova and V. Percec, Polym. Chem., 2013, 4, 2424 DOI: 10.1039/C3PY00220A

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