Issue 4, 2013
From the journal:

Polymer Chemistry

Anchimeric assistance on sequence regulation in partial modification of isotactic poly(propargyl methacrylate) by click reaction

Takehiro Kitaura,a   Hiroshi Tomioka,a   Noriyuki Fukatania  and  Tatsuki Kitayama*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka, Japan
E-mail: kitayama@chem.es.osaka-u.ac.jp

Abstract

Cu-catalyzed click reaction of highly isotactic poly(propargyl methacrylate) with organic azides with a weakly coordinating monoamine was found to proceed to form blocky segments from 1H NMR observation of monomer-sequence sensitive peak-splittings in the partially modified polymer, while the reaction with a highly coordinative triamine proceeded in a random fashion along the polymer chain.

Graphical abstract: Anchimeric assistance on sequence regulation in partial modification of isotactic poly(propargyl methacrylate) by click reaction

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Article information

DOI
https://doi.org/10.1039/C2PY20996A
Article type
Communication
Submitted
18 Nov 2012
Accepted
08 Dec 2012
First published
10 Dec 2012

Polym. Chem., 2013,4, 887-890

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Anchimeric assistance on sequence regulation in partial modification of isotactic poly(propargyl methacrylate) by click reaction

T. Kitaura, H. Tomioka, N. Fukatani and T. Kitayama, Polym. Chem., 2013, 4, 887 DOI: 10.1039/C2PY20996A

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