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Issue 44, 2013
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NaH mediated isomerisation–allylation reaction of 1,3-substituted propenols

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Abstract

A base mediated isomerisation–allylation protocol of 1,3-disubstituted propenols has been established. The use of diaryl and aryl-silyl substrates is reported alongside the use of substituted allyl bromides. Mechanistic experiments have also been conducted to elucidate the reaction pathway.

Graphical abstract: NaH mediated isomerisation–allylation reaction of 1,3-substituted propenols

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Publication details

The article was received on 11 Sep 2013, accepted on 03 Oct 2013 and first published on 03 Oct 2013


Article type: Communication
DOI: 10.1039/C3OB41857J
Citation: Org. Biomol. Chem., 2013,11, 7662-7666
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    NaH mediated isomerisation–allylation reaction of 1,3-substituted propenols

    A. J. S. Johnston, M. G. McLaughlin, J. P. Reid and M. J. Cook, Org. Biomol. Chem., 2013, 11, 7662
    DOI: 10.1039/C3OB41857J

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