Jump to main content
Jump to site search

Issue 43, 2013
Previous Article Next Article

Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols

Author affiliations

Abstract

Allyl amides were synthesised from the reaction of allyl alcohols and halogenated nitriles using a platinum multifaceted catalysis approach in which both the nucleophilic addition and subsequent [3,3]-sigmatropic rearrangement steps of the process were catalysed by the same complex. Additionally, 1H/13C{1H} NMR and GC studies provided the first insights into the mechanism of this transformation.

Graphical abstract: Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols

Back to tab navigation

Supplementary files

Article information


Submitted
18 Aug 2013
Accepted
03 Sep 2013
First published
26 Sep 2013

Org. Biomol. Chem., 2013,11, 7472-7476
Article type
Paper

Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols

R. P. Lester, J. J. Dunsford and J. E. Camp, Org. Biomol. Chem., 2013, 11, 7472
DOI: 10.1039/C3OB41692E

Social activity

Search articles by author

Spotlight

Advertisements