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Issue 33, 2013
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Meta-arylation of calixarenes using organomercurial chemistry

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Abstract

A direct mercuration reaction combined with a subsequent Pd-catalyzed arylation was used to introduce the aryl moiety into the meta position of the calix[4]arene skeleton. The application of organomercurial intermediates thus allows the straightforward formation of meta-aryl-substituted derivatives representing a unique substitution pattern in calixarene chemistry.

Graphical abstract: Meta-arylation of calixarenes using organomercurial chemistry

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Publication details

The article was received on 24 May 2013, accepted on 02 Jul 2013 and first published on 02 Jul 2013


Article type: Paper
DOI: 10.1039/C3OB41085D
Org. Biomol. Chem., 2013,11, 5528-5534

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    Meta-arylation of calixarenes using organomercurial chemistry

    P. Slavík, K. Flídrová, H. Dvořáková, V. Eigner and P. Lhoták, Org. Biomol. Chem., 2013, 11, 5528
    DOI: 10.1039/C3OB41085D

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