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Issue 33, 2013
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Meta-arylation of calixarenes using organomercurial chemistry

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Abstract

A direct mercuration reaction combined with a subsequent Pd-catalyzed arylation was used to introduce the aryl moiety into the meta position of the calix[4]arene skeleton. The application of organomercurial intermediates thus allows the straightforward formation of meta-aryl-substituted derivatives representing a unique substitution pattern in calixarene chemistry.

Graphical abstract: Meta-arylation of calixarenes using organomercurial chemistry

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Article information


Submitted
24 May 2013
Accepted
02 Jul 2013
First published
02 Jul 2013

Org. Biomol. Chem., 2013,11, 5528-5534
Article type
Paper

Meta-arylation of calixarenes using organomercurial chemistry

P. Slavík, K. Flídrová, H. Dvořáková, V. Eigner and P. Lhoták, Org. Biomol. Chem., 2013, 11, 5528
DOI: 10.1039/C3OB41085D

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