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Issue 15, 2013
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Asymmetric synthesis of cyclo-archaeol and β-glucosyl cyclo-archaeol

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Abstract

An efficient asymmetric synthesis of cyclo-archaeol and β-glucosyl cyclo-archaeol is presented employing catalytic asymmetric conjugate addition and catalytic epoxide ring opening as the key steps. Their occurrence in deep sea hydrothermal vents has been confirmed by chromatographic comparison with natural samples.

Graphical abstract: Asymmetric synthesis of cyclo-archaeol and β-glucosyl cyclo-archaeol

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Publication details

The article was received on 23 Nov 2012, accepted on 12 Feb 2013 and first published on 12 Feb 2013


Article type: Paper
DOI: 10.1039/C3OB27277J
Citation: Org. Biomol. Chem., 2013,11, 2482-2492

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    Asymmetric synthesis of cyclo-archaeol and β-glucosyl cyclo-archaeol

    C. Ferrer, P. Fodran, S. Barroso, R. Gibson, E. C. Hopmans, J. S. Damsté, S. Schouten and A. J. Minnaard, Org. Biomol. Chem., 2013, 11, 2482
    DOI: 10.1039/C3OB27277J

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