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Issue 24, 2013
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Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles

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Abstract

The palladium-catalyzed three-component reactions of benzyl halides, activated olefins, and allyltributylstannane were successfully conducted to produce the corresponding benzylallylation products in satisfactory to high yields. The benzylallylation reaction proceeded smoothly under mild conditions in the presence of palladium nanoparticles in tetrahydrofuran.

Graphical abstract: Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles

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Publication details

The article was received on 09 Mar 2013, accepted on 16 Apr 2013 and first published on 16 Apr 2013


Article type: Paper
DOI: 10.1039/C3OB40487K
Org. Biomol. Chem., 2013,11, 4016-4024

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    Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles

    X. Zhang, X. Feng, X. Yu, R. He and M. Bao, Org. Biomol. Chem., 2013, 11, 4016
    DOI: 10.1039/C3OB40487K

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