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Issue 23, 2013
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Frequency spectroscopy of irreversible electrochemical nucleation kinetics on the nanoscale

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Abstract

An approach is developed for probing the thermodynamics and kinetics of irreversible electrochemical reactions on solid surfaces based on local frequency-voltage spectroscopy. For a model Li-ion conductor surface, two regimes for bias-controlled behavior are demonstrated and ascribed to the difference in the critical nucleus size. The electrostatic and electrochemical phenomena at the tip-surface junction are analyzed. These studies suggest an experimental pathway for exploring local electrochemical activity in solids.

Graphical abstract: Frequency spectroscopy of irreversible electrochemical nucleation kinetics on the nanoscale

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Publication details

The article was received on 30 Jul 2013, accepted on 24 Sep 2013 and first published on 27 Sep 2013


Article type: Paper
DOI: 10.1039/C3NR03953F
Citation: Nanoscale, 2013,5, 11964-11970

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    Frequency spectroscopy of irreversible electrochemical nucleation kinetics on the nanoscale

    A. Kumar, C. Chen, T. M. Arruda, S. Jesse, F. Ciucci and S. V. Kalinin, Nanoscale, 2013, 5, 11964
    DOI: 10.1039/C3NR03953F

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