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Issue 11, 2013
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Evidence of the unprecedented conversion of intermolecular proton to water bridging of two phosphoryl ruthenium complexes

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Abstract

We evidenced the conversion of an unprecedented intermolecular bridged-proton bimetallic P-metallated phosphoryl complex [{[Ru](Ph2P[double bond, length as m-dash]O)}2H][PF6]3 to its corresponding H-bonded water complex [{[Ru](Ph2P[double bond, length as m-dash]O)}2(H2O)][PF6]2, a rare motif. Their synthesis, NMR data, X-ray crystal structures, electrochemical and photophysical properties are reported.

Graphical abstract: Evidence of the unprecedented conversion of intermolecular proton to water bridging of two phosphoryl ruthenium complexes

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Publication details

The article was received on 17 May 2013, accepted on 08 Aug 2013 and first published on 08 Aug 2013


Article type: Paper
DOI: 10.1039/C3NJ00522D
Citation: New J. Chem., 2013,37, 3543-3548
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    Evidence of the unprecedented conversion of intermolecular proton to water bridging of two phosphoryl ruthenium complexes

    R. Sylvain, L. Vendier, C. Bijani, A. Santoro, F. Puntoriero, S. Campagna, P. Sutra and A. Igau, New J. Chem., 2013, 37, 3543
    DOI: 10.1039/C3NJ00522D

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