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Issue 6, 2013
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DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and α-fluorinated sulfones

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Abstract

A DIAD-mediated metal-free cross dehydrogenative coupling involving aliphatic tertiary amines and α-fluorinated sulfones leading to β-fluorinated amines was developed. This protocol represents the first direct fluoroalkylation of C–H bonds with hydrofluorocarbon derivatives (RF–H).

Graphical abstract: DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and α-fluorinated sulfones

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Article information


Submitted
17 Sep 2012
Accepted
16 Oct 2012
First published
17 Oct 2012

New J. Chem., 2013,37, 1684-1687
Article type
Letter

DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and α-fluorinated sulfones

W. Huang, C. Ni, Y. Zhao and J. Hu, New J. Chem., 2013, 37, 1684
DOI: 10.1039/C2NJ40842B

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