Co3O4 co-doped TiO2nanoparticles as a selective marker of lead in aqueous solution

Abstract

Co₃O₄ co-doped TiO₂ nanoparticles were prepared by a low temperature thermal method and their functional relationships with metal ions was investigated using solid phase extraction. The analytical potential of Co₃O₄ co-doped TiO₂ nanoparticles was studied for the selective extraction of lead using inductively coupled plasma-optical emission spectrometry. The selectivity of Co₃O₄ co-doped TiO₂ nanoparticles was investigated toward different metal ions, including Cd(II), Co(II), Cr(III), Cu(II), Fe(II and III), Hg(II), La(III), Mn(II), Ni(II), Pb(II), Pd(II) and Y(III). Data obtained from the selectivity study showed that Co₃O₄ co-doped TiO₂ nanoparticles have the highest selectivity toward Pb(II). The uptake capacity for Pb(II) was experimentally calculated to be 114.05 mg g⁻¹. Moreover, adsorption isotherm data of Pb(II) on Co₃O₄ co-doped TiO₂ nanoparticles fit well with the Langmuir adsorption isotherm, strongly supporting that the adsorption process was mainly as a monolayer on Co₃O₄ co-doped TiO₂ nanoparticle surfaces.