Issue 6, 2013
From the journal:

New Journal of Chemistry

DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and α-fluorinated sulfones†

Weizhou Huang,a   Chuanfa Ni,a   Yanchuan Zhaoa  and  Jinbo Hu*a  

* Corresponding authors

a Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai 200032, China
E-mail: jinbohu@sioc.ac.cn
Tel: +86-21-54925174

Abstract

A DIAD-mediated metal-free cross dehydrogenative coupling involving aliphatic tertiary amines and α-fluorinated sulfones leading to β-fluorinated amines was developed. This protocol represents the first direct fluoroalkylation of C–H bonds with hydrofluorocarbon derivatives (RF–H).

Graphical abstract: DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and α-fluorinated sulfones

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Article information

DOI
https://doi.org/10.1039/C2NJ40842B
Article type
Letter
Submitted
17 Sep 2012
Accepted
16 Oct 2012
First published
17 Oct 2012

New J. Chem., 2013,37, 1684-1687

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DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and α-fluorinated sulfones

W. Huang, C. Ni, Y. Zhao and J. Hu, New J. Chem., 2013, 37, 1684 DOI: 10.1039/C2NJ40842B

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