Jump to main content
Jump to site search

Issue 1, 2014
Previous Article Next Article

Biomimetic di-manganese catalyst cage-isolated in a MOF: robust catalyst for water oxidation with Ce(iv), a non-O-donating oxidant

Author affiliations

Abstract

A biomimetic di-Mn catalyst catalyzes water oxidation with (NH4)2Ce(NO3)6 for >7 days with initial TOF of 40 h−1. Isolation of one molecule of catalyst in each pore of a Cr-based MOF prevents decomposition of the catalyst and allows sustained water oxidation even at pH 1.00.

Graphical abstract: Biomimetic di-manganese catalyst cage-isolated in a MOF: robust catalyst for water oxidation with Ce(iv), a non-O-donating oxidant

Back to tab navigation

Supplementary files

Article information


Submitted
10 Sep 2013
Accepted
30 Oct 2013
First published
04 Nov 2013

Energy Environ. Sci., 2014,7, 317-322
Article type
Communication

Biomimetic di-manganese catalyst cage-isolated in a MOF: robust catalyst for water oxidation with Ce(IV), a non-O-donating oxidant

R. E. Hansen and S. Das, Energy Environ. Sci., 2014, 7, 317
DOI: 10.1039/C3EE43040E

Social activity

Search articles by author

Spotlight

Advertisements