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Issue 47, 2013
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From a mononuclear NiII precursor to antiferromagnetically coupled trinuclear double-stranded helicates

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Abstract

Reaction of the mononuclear NiII complex [Ni{2-Py(6-NH2)NHC(S)NP(S)(OiPr)2}2] with different salicylaldehydes leads to new antiferromagnetically coupled trinuclear double-stranded helicates 1–3, where NiII metal ions are coordinated by two bis-anionic thiourea ligands and two deprotonated molecules of the corresponding aldehyde.

Graphical abstract: From a mononuclear NiII precursor to antiferromagnetically coupled trinuclear double-stranded helicates

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Article information


Submitted
29 Aug 2013
Accepted
24 Sep 2013
First published
15 Oct 2013

Dalton Trans., 2013,42, 16470-16473
Article type
Communication

From a mononuclear NiII precursor to antiferromagnetically coupled trinuclear double-stranded helicates

D. A. Safin, M. G. Babashkina, K. Robeyns, M. Rouzières, R. Clérac and Y. Garcia, Dalton Trans., 2013, 42, 16470
DOI: 10.1039/C3DT52387J

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