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Issue 32, 2013
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Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents

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Abstract

Herein we report the synthesis of α-Dawson type POM, Li6[α-P2W18O62]·28H2O, directly from the use of Li2WO4 as the tungstate source. The salt obtained was soluble not only in water but also in a range of polar and non-polar organic solvents, such as benzene.

Graphical abstract: Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents

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Article information


Submitted
29 Apr 2013
Accepted
17 Jun 2013
First published
08 Jul 2013

Dalton Trans., 2013,42, 11363-11366
Article type
Communication

Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents

C. Kato, S. Nishihara, R. Tsunashima, Y. Tatewaki, S. Okada, X. Ren, K. Inoue, D. Long and L. Cronin, Dalton Trans., 2013, 42, 11363
DOI: 10.1039/C3DT51120K

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