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Issue 19, 2013
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Synthesis and characterization of a tetrathiafulvalene-salphen actinide complex

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Abstract

A new tetrathiafulvalene-salphen uranyl complex has been prepared. The system was designed to study the electronic coupling between actinides and a redox active ligand framework. Theoretical and experimental methods – including DFT calculations, single crystal X-ray analysis, cyclic voltammetry, NMR and IR spectroscopies – were used to characterize this new uranyl complex.

Graphical abstract: Synthesis and characterization of a tetrathiafulvalene-salphen actinide complex

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Publication details

The article was received on 14 Mar 2013, accepted on 15 Mar 2013 and first published on 09 Apr 2013


Article type: Communication
DOI: 10.1039/C3DT50698C
Citation: Dalton Trans., 2013,42, 6716-6719
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    Synthesis and characterization of a tetrathiafulvalene-salphen actinide complex

    C. Bejger, Y. Tian, B. J. Barker, K. S. Boland, B. L. Scott, E. R. Batista, S. A. Kozimor and J. L. Sessler, Dalton Trans., 2013, 42, 6716
    DOI: 10.1039/C3DT50698C

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