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Issue 18, 2013
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Chiral MOP-phosphonite ligands: synthesis, characterisation and interconversion of η16-(σ-P, π-arene) chelated rhodium(i) complexes

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Abstract

The synthesis of rhodium(I) and iridium(I) complexes of chiral MOP-phosphonite ligands is reported. The full characterisation of η16-(σ-P, π-arene) chelated 18VE rhodium(I) complexes reveals hemilabile binding on the arene which has been quantitatively analysed.

Graphical abstract: Chiral MOP-phosphonite ligands: synthesis, characterisation and interconversion of η1,η6-(σ-P, π-arene) chelated rhodium(i) complexes

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Article information


Submitted
11 Dec 2012
Accepted
22 Feb 2013
First published
25 Mar 2013

This article is Open Access

Dalton Trans., 2013,42, 6302-6305
Article type
Communication

Chiral MOP-phosphonite ligands: synthesis, characterisation and interconversion of η16-(σ-P, π-arene) chelated rhodium(I) complexes

A. Ficks, R. W. Harrington and L. J. Higham, Dalton Trans., 2013, 42, 6302
DOI: 10.1039/C3DT50482D

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