Chiral MOP-phosphonite ligands: synthesis, characterisation and interconversion of η1,η6-(σ-P, π-arene) chelated rhodium(I) complexes

Arne Ficks; Ross W. Harrington; Lee J. Higham

doi:10.1039/C3DT50482D

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Chiral MOP-phosphonite ligands: synthesis, characterisation and interconversion of η¹,η⁶-(σ-P, π-arene) chelated rhodium(i) complexes†

Arne Ficks,^a Ross W. Harrington^a and Lee J. Higham*^a

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* Corresponding authors

^a School of Chemistry, Newcastle University, Bedson Building, Newcastle upon Tyne, NE1 7RU, UK
E-mail: lee.higham@ncl.ac.uk
Fax: +44 (0)191 222 6929
Tel: +44 (0)191 222 5542

Abstract

The synthesis of rhodium(I) and iridium(I) complexes of chiral MOP-phosphonite ligands is reported. The full characterisation of η¹,η⁶-(σ-P, π-arene) chelated 18VE rhodium(I) complexes reveals hemilabile binding on the arene which has been quantitatively analysed.

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Article information

DOI: https://doi.org/10.1039/C3DT50482D
Article type: Communication
Submitted: 11 Dec 2012
Accepted: 22 Feb 2013
First published: 25 Mar 2013
This article is Open Access

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Dalton Trans., 2013,42, 6302-6305

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Chiral MOP-phosphonite ligands: synthesis, characterisation and interconversion of η¹,η⁶-(σ-P, π-arene) chelated rhodium(I) complexes

A. Ficks, R. W. Harrington and L. J. Higham, Dalton Trans., 2013, 42, 6302 DOI: 10.1039/C3DT50482D

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Dalton Transactions