Issue 40, 2013
From the journal:

Dalton Transactions

Synthesis, structures and hydrogen storage properties of two new H-enriched compounds: Mg(BH4)2(NH3BH3)2 and Mg(BH4)2·(NH3)2(NH3BH3)†

Xiaowei Chen,‡a   Feng Yuan,‡a   Qinfen Gub  and  Xuebin Yu*a  

* Corresponding authors

a Department of Materials Science, Fudan University, Shanghai 200433, China
E-mail: yuxuebin@fudan.edu.cn

b Australian Synchrotron, Clayton, Victoria 3168, Australia

Abstract

The synthesis, crystal structure and dehydrogenation performances of two new H-enriched compounds, Mg(BH4)2(NH3BH3)2 and Mg(BH4)2·(NH3)2(NH3BH3), are reported. Due to the introduction of ammonia ligands, the Mg(BH4)2·(NH3)2(NH3BH3) exhibits dramatically improved dehydrogenation properties over its parent compound.

Graphical abstract: Synthesis, structures and hydrogen storage properties of two new H-enriched compounds: Mg(BH4)2(NH3BH3)2 and Mg(BH4)2·(NH3)2(NH3BH3)

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Article information

DOI
https://doi.org/10.1039/C3DT52203B
Article type
Communication
Submitted
28 Jun 2013
Accepted
16 Aug 2013
First published
19 Aug 2013

Dalton Trans., 2013,42, 14365-14368

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Synthesis, structures and hydrogen storage properties of two new H-enriched compounds: Mg(BH4)2(NH3BH3)2 and Mg(BH4)2·(NH3)2(NH3BH3)

X. Chen, F. Yuan, Q. Gu and X. Yu, Dalton Trans., 2013, 42, 14365 DOI: 10.1039/C3DT52203B

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