A 3d–4f heterometallic 3D POMOF based on lacunary Dawson polyoxometalates†
Abstract
A novel compound, Na2[Ce4(H2O)22(dpdo)5](Mn2HP2W15O56)2·8H2O (1) (dpdo = 4,4′-bipyridine-N,N′-dioxide) with 3d–4f heterometallic 3D POMOF that can be described as a self-penetrating (4,4,6)-connected net topology, has been isolated via a stepwise method, and its magnetic and electrocatalytic properties have been investigated.