Issue 36, 2013
From the journal:

Dalton Transactions

Ionothermal synthesis of two oxalate-bridged lanthanide(iii) chains with slow magnetization relaxation by using a deep eutectic solvent†

Yan Meng,a   Jun-Liang Liu,a   Ze-Min Zhang,a   Wei-Quan Lin,a   Zhuo-Jia Lina  and  Ming-Liang Tong*a  

* Corresponding authors

a Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, P. R. China
E-mail: tongml@mail.sysu.edu.cn

Abstract

Two novel isostructural oxalate-bridged lanthanide(III) chains, (choline)[Ln(ox)(H2O)3Cl]Cl·H2O (Ln = Dy/Er), were first obtained ionothermally by using a choline chloride–oxalic acid eutectic mixture as both solvent and structure-directing agent, both of which show field-induced slow relaxation of magnetization.

Graphical abstract: Ionothermal synthesis of two oxalate-bridged lanthanide(iii) chains with slow magnetization relaxation by using a deep eutectic solvent

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Article information

DOI
https://doi.org/10.1039/C3DT51816G
Article type
Communication
Submitted
01 Jun 2013
Accepted
10 Jul 2013
First published
11 Jul 2013

Dalton Trans., 2013,42, 12853-12856

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Ionothermal synthesis of two oxalate-bridged lanthanide(III) chains with slow magnetization relaxation by using a deep eutectic solvent

Y. Meng, J. Liu, Z. Zhang, W. Lin, Z. Lin and M. Tong, Dalton Trans., 2013, 42, 12853 DOI: 10.1039/C3DT51816G

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