Issue 37, 2013
From the journal:

Dalton Transactions

Borate-templated self-assembly of multinuclear nickel(ii)-containing POMs†

Shujun Li,a   Shuxia Liu,*a   Qun Tang,a   Yiwei Liu,a   Danfeng He,a   Shengtian Wanga  and  Zhan Shib  

* Corresponding authors

a Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, PR China
E-mail: liusx@nenu.edu.cn
Fax: +86-431-85099328
Tel: +86-431-85099328

b State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, PR China

Abstract

Two unprecedented nickel–boron cluster-containing POMs have been isolated through a facile approach by the reactions of trivacant [A-α-SiW9O34]10− and Ni2+ in borate buffer. The {BO3} and {B2O4(OH)2} units enclosed in the Ni8 cluster of 1 and the Ni12 cluster of 2 play important templating roles in the assembly of the target compounds.

Graphical abstract: Borate-templated self-assembly of multinuclear nickel(ii)-containing POMs

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3DT51201K
Article type
Communication
Submitted
07 May 2013
Accepted
15 Jul 2013
First published
17 Jul 2013

Dalton Trans., 2013,42, 13319-13322

Permissions

Request permissions

Borate-templated self-assembly of multinuclear nickel(II)-containing POMs

S. Li, S. Liu, Q. Tang, Y. Liu, D. He, S. Wang and Z. Shi, Dalton Trans., 2013, 42, 13319 DOI: 10.1039/C3DT51201K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements